Adrian Chiles is joined by Steve McManaman, Paul Scholes and Lee Dixon in the Bernabeu Stadium as Liverpool play their toughest group match against reigning European champions Real Madrid.
After just three points from their first three games, the Reds face an uphill challenge to qualify for the last 16.
Brendan Rodgers' side were humbled at Anfield last time out as Ronaldo and co. ran riot at Anfield in a three-nil win, will they do better this time?
Real Madrid v Liverpool - Tuesday 4th November, ITV, 7:30pm.
CSKA Moscow have had their punishment for racist behaviour by fans reduced on appeal by UEFA, meaning they only have to play one more Champions League game behind closed doors.
Liverpool vice-captain Jordan Henderson admits the lesson they were taught by Real Madrid shows just how much they have to improve to compete with Europe's elite.
Cristiano Ronaldo's goal against Liverpool last night saw him extend his run of scoring in consecutive games to double figures.
Liverpool striker Mario Balotelli will be reprimanded by manager Brendan Rodgers after swapping shirts with Real Madrid's Pepe with his side 3-0 down at half-time.
Former Liverpool defender Jamie Carragher does not believe Mario Balotelli will remain with the club next season, and has labelled the controversial forward a panic buy.
Cristiano Ronaldo saluted another "fantastic" Real Madrid performance as the European champions claimed a comprehensive 3-0 win at Liverpool.
Ronaldo himself was in scintillating form, opening the scoring in their Champions League Group B encounter midway through the first half with a tremendous half-volley finish from James Rodriguez's delightful chip.