Charnwood College, formerly Burleigh Community College, has seen 97% of students achieve five A* - C grades, 3% up on last year.
92 students (34.3%) gained three or more A* or A grades and 99% achieved at least one GCSE pass.
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A Leicester City fan who put a £5 bet on a 5000-1 that his team would win the Premier League could find himself £25,000 richer.
He will be replaced by Academy Director and former Rams defender Darren Wassall until the end of the season.
The boy, 7 and girl, 4, were pulled from the rubble by the fire service and airlifted to Birmingham Children's hospital.