Lottery operator Camelot says that the £64 million win would be the largest ever to go unclaimed.
Hertfordshire residents are being urged to check their pockets, cars and sofas for the missing ticket.
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Camden Council is evacuating four tower blocks in the Chalcots estate in north London, to allow "urgent fire safety works" to take place.
Scotland Yard said it was taking action under public order laws over the marches "due to concerns of serious public disorder".
The Football Association says it is hoped that the match will raise around £1.25million for the victims.