Unveiling a portrait of Dr Chad Varah, the charity's founder, the Prince of Wales said: "I am deeply appreciative and full of admiration of everything these remarkable volunteers do; that you give up so much of your time and provide your love and compassion in this way."
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The new list is the first to be published since the general election. Some of those identified owed money to a handful of workers.
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The first Blue Moon since 2012 will appear over the UK on Friday. The next won't be until 2018.