Crews used 10 breathing apparatus, two hose reels, two jets, two compressed air foam jets and the aerial ladder platform to bring the fire at Winton School in Andover under control.
Group Manager Dan Tasker said: "The first crews to arrive were met with a challenging situation of a confirmed fire plus the evacuation of 500 pupils."
More top news
Fly-tipping figures may not show full extent of dumping problem, a Meridian investigation reveals
Tuesday afternoon's weather for the west of the region
Tuesday afternoon's weather for the east of the region