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The new rules to ban "rip-off" charges for people who use debit or credit cards to buy goods and services have been welcomed by consumer campaigners, who say businesses must not try to pass on costs in other ways.
Richard Lloyd, Which? executive director, said: "Over 50,000 people supported our campaign to end rip-off surcharges so we're pleased the Government is implementing this ban.
"For it to be effective there must be a tough enforcement regime and companies must play fair and not pass costs on to customers in other ways.
"We will be monitoring the ban closely and want people to tell us about surcharges they think are excessive."
The measures are being implemented through the Consumer Rights (Payment Surcharges) Regulations 2012.
Micro businesses and business start-ups will be exempt from the regulations until June 2014, allowing them more time to prepare.
Research conducted by the Office of Fair Trading (OFT) in 2010 found that 87% of consumers objected to extra charges for credit cards and 91% objected to extra charges for debit cards.
Consumer Minister Jo Swinson said the practice of "rip-off" charges for consumers had been happening "for far too long".
"They are fed up of thinking they will be paying a certain price for goods only to find out towards the end of the process that the final price is much higher."
Ms Swinson said the ban will stop retailers from cashing in by charging add-on fees that do not reflect the cost of processing the payment.
A ban on "rip-off" charges for people who use debit or credit cards to buy goods and services such as flights and cinema tickets began today.
Under the new rules, traders should make sure that any payment surcharges reflect the actual processing cost involved and are not excessive.
The crackdown aims to make payments more transparent for consumers so they are not hit with a "nasty surprise" at the end of the payment process.
The Office of Fair Trading (OFT) estimates that consumers spent around #300 million on payment surcharges in 2010 in the airline sector alone.
Surcharges are often imposed in other sectors, including rail, event tickets, cinemas, car dealerships and hotels.