Among the new wave of UTCs is Warwick, Cambridge and Hertfordshire - which will train 600 pupils in two specialisms - entertainment technologies and crafts, and electronic engineering and digital technology.
UTCs are also to be established in Swindon, Bluewater, Barking and Dagenham, Norfolk, Harlow, Lincoln, Coventry, Birkenhead, Liverpool and Cumbria.
Two UTCs are already open, the JCB Academy in Staffordshire, and the Black Country UTC in Walsall. 17 are in the pre-opening phase, with three due to open in September.
Fifteen new university technical colleges linked to firms including Virgin Atlantic and Jaguar Land Rover are to open within two years, the Government said.
Around 200 employers are linked to the new institutions, which offer pupils aged 14 to 19 a technical and engineering focus alongside academic study.
The 15 new state-funded colleges - which will each focus on a local industry or trade - are all linked to institutions including universities and businesses and will open in 2013 and 2014. They will join a network of 17 UTCs due to open this September or next.