Labour is drawing up its own draft legislation to demonstrate that Leveson's recommendations could be implemented without the difficulties feared by ministers.
The opposition's Bill is expected to be completed before Christmas, paving the way for Labour to force a Commons vote by the end of January if no agreement is reached in cross-party talks.
The result would not be binding on the Government, but a defeat could be hugely damaging for the Prime Minister.
As the editors met at Number 10, Labour leader Ed Miliband hosted talks in his office with representatives of the Hacked Off campaign group, including phone hacking victims.
"What I heard from the victims of sections of the press is that they are pleased there are good intentions from the editors but they want more than good intentions," he said.
"They want the force of law to make sure those good intentions are turned into reality."
He said he did not doubt the goodwill of the editors to reform, "but we have no guarantee that that goodwill and those good words are actually going to mean something on an ongoing basis".
More top news
Kate will join Prince William on a tour of the Stephen Lawrence Centre before visiting a charity working with disadvantaged young people.
There is an "urgent need" for a "simpler and more trusted" system for investigating clinical failures, according to a damning report.
Over 100 mothers and fathers were investigated for leaving their children unsupervised in the final three months of 2014, new figures find.