Dr Sarah Jarvis has told Daybreak that it would be "difficult" to impose a seven-day rule on GPs and hospitals.
She said: "This is not going to be free, there's going to be a lot of bureaucracy and that means more cost for the NHS and patient care would suffer."
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The Labour leader did not say whether he would maintain Britain's nuclear deterrent programme.
Ukip leader Paul Nuttall also said he would want to get rid of Sharia courts.
Over 40,000 people picked up their packs to take part in the annual marathon in the capital.