London Mayor Boris Johnson has been wheeled out throughout the year in promotion of the RideLondon cycling festival.
The regular rider will take part in the 100-mile challenge on Sunday.
"My team has told me I will never make it," Mr Johnson said. "They think I am too clapped out to cycle 100 miles but the more they discourage me, the more determined I am to have a crack."
More top news
Andreea Cristea, 29, remains in a critical condition after being rescued from the Thames after a terror attack along Westminster Bridge.
The Prime Minister has praised the former soldier's "huge professionalism" in trying to save the life of Pc Keith Palmer.
The man who carried out the Westminster attack is thought to be British born and was once investigated by MI5, the Prime Minister has said.