Three men, aged 53, 38 and 20 years old from the St Brides area of Newport, have been arrested on suspicion of slavery and servitude offences, Gwent Police said.
Four other suspects remain in custody and are assisting officers with their enquiries after the granting of a further 24 hours in custody by a District Judge.
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The Metropolitan Police Federation, which set up the official JustGiving site, said it felt a "suitable amount" had been collected.
There is no evidence the Westminster attacker Khalid Masood was associated with so-called Islamic State or al Qaeda, the Met Police said.
Janet Ajao said in a statement: "I do not condone his actions nor support the beliefs he held that led to him committing this atrocity."