The house fire that left two women and three children dead was "severe", a spokesman for South Yorkshire Fire and Rescue said.
He said: "Our investigators are arriving here at 9am, so we we will know more later on this morning."
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Accompanied by the Duke of Edinburgh, the Queen will attend the opening ceremony of the fifth session in the Holyrood chamber.
Ms Leadsom has received the backing of Ian Duncan Smith, the former work and pensions secretary.
The former shadow work and pensions secretary is considered a more viable candidate than Angela Eagle, a Labour source has told ITV News.