ITV News footage shows a confrontation between Ukrainian forces and local men in the eastern city of Mariupol.
The troops retreat from unarmed locals who are walking towards them shouting. The troops can then be seen repeatedly firing into the air to warn the men off.
European Union foreign ministers added 13 people to their visa ban and asset freeze list over Ukraine's crisis.
Well that’s the voting over, and no surprises so far. A ‘Yes’ vote claimed to be 89% in Donetsk, and suddenly Ukraine is no more.
Nearly 90 percent of voters in eastern Ukrainian region voted for self-rule, the head of the separatist election commission said.