One died and a second was wounded after the Ukrainian National Guard tried to disperse a crowd at a municipal building - Interfax-Ukraine news agency has said.
Members of the Guard's "Dnipr" battalion fired shots as a crowd tried to block their entry into the building. It gave no details of the shooting.
European Union foreign ministers added 13 people to their visa ban and asset freeze list over Ukraine's crisis.
Well that’s the voting over, and no surprises so far. A ‘Yes’ vote claimed to be 89% in Donetsk, and suddenly Ukraine is no more.
Nearly 90 percent of voters in eastern Ukrainian region voted for self-rule, the head of the separatist election commission said.