US Secretary of State John Kerry warned Russia that it must not intervene in Ukraine under the "pretext of peacekeeping", his department said.
The statement follows Russia's version of the call, in which its Foreign Minister Sergei Lavrov was said to have called for urgent measures to avert a "humanitarian catastrophe" in the east of the country.
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There will be blustery showers across northern parts overnight with showery rain and sleet across the south.