On her first day in post, Meri Huws says her role is about protecting the rights of Welsh speakers.
She says she will use her enforcement powers if necessary, but says her target won't be small businesses in predominantly English-speaking areas, the proverbial 'Chepstow chip shops.'
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Low cloud will bring murky conditions with extensive hill fog.
The team, which is manned by volunteers, will operate out of Pontardawe Fire Station in partnership with Mid and West Wales Fire Service.
Dan Biggar has no doubt that Wales remain flrmly in the Six Nations title mix ahead of next Saturday's clash against Scotland.