Marc Thompson said the "hardest thing is not knowing" where his twin brother Ben is.
The 34-year-old from Haverfordwest has been missing since Saturday, after he watched Wales' Six Nations game at the Millennium Stadium.
He told our Correspondent Carole Green that this would be "very out of character" for him not to contact his family.
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Cloud will thicken across all parts overnight with outbreaks of rain.
The Football Association of Wales said it is 'delighted' to be offered a chance to bid.
Ifthir Ahmed told ITV News 'a lot of work' is being done in Newport in an attempt to prevent extremism within the community.