CITV Ultimate Spider-Man Catch up on the ITV Hub Ultimate Spider-Man tells a coming of age story, where hapless Peter Parker evolves from a naive teen hotshot to a true hero after being bitten by a genetically altered spider and inheriting its powers. 3 episodes available to watch Share this programme: Share on Facebook Share on Twitter Share on Google+ Series 4 Latest 8. Episode 0008 Sun Sunday 21 Jan 7.05am Doc Ock creates Anti-Venom in order to destroy one of the Web Warriors. 7. Beached Sat Saturday 20 Jan 7.05am Doc Ock has captured Sandman and is trying to clone him. Series 3 25. Contest of Champions (Part 3) Sat Saturday 16 Dec 7.10am Spider-Man has to change the rules of The Grandmaster's game.